A study on the interaction between ferric ion and silicic acid in hydrosphere: Si-containing ferruginous deposits formed in neutral hot spring waters     

Gaowa Naren  Akane Miyazaki  Motoyuki Matsuo  BAI Shuqin  Kotaro Yonesu  Yoshihiro Okaue  Takushi Yokoyama 《中国地球化学学报》2013,32(1):27-34

Five ferruginous deposit samples formed from neutral hot springs were analyzed to determine whether they consisted of a mixture of silica, hydrous iron oxide or iron silicate by differential thermal analysis (DTA), infrared (IR) spectroscopy, powder X-ray diffraction (XRD), and 57Fe Mssbauer spectroscopy. The Si/Fe atomic ratios of the deposits ranged from 0.25 to 0.45, and were smaller than those of hisingerite (12), but apparently close to those of siliceous ferrihydrite (0.250.5). Si was confirmed to be present as monomeric or oligomeric silicate from the Si-O stretching vibration frequencies on the IR spectra. Judging from the results of DTA, which minerals starting to produce after heating, and a relationship between Si-O stretching vibration frequency and Si/Fe atomic ratio proposed by Henmi et al. (1981), all the deposits in this study were concluded to be mixtures of various siliceous ferri-hydrites with low and high Si/Fe atomic ratios. Moreover, by comparing the chemical properties of hot spring waters, the formation conditions of siliceous ferrihydrite were also discussed.  相似文献   

Dynamics of Enceladus and Dione inside the 2:1 mean-motion resonance under tidal dissipation     

N. CallegariJr  T. Yokoyama 《Celestial Mechanics and Dynamical Astronomy》2008,102(4):273-296

In a previous work (Callegari and Yokoyama, Celest. Mech. Dyn. Astr. 98:5–30, 2007), the main features of the motion of the pair Enceladus–Dione were analyzed in the frozen regime, i.e., without considering the tidal evolution. Here, the results of a great deal of numerical simulations of a pair of satellites similar to Enceladus and Dione crossing the 2:1 mean-motion resonance are shown. The resonance crossing is modeled with a linear tidal theory, considering a two-degrees-of-freedom model written in the framework of the general three-body planar problem. The main regimes of motion of the system during the passage through resonance are studied in detail. We discuss our results comparing them with classical scenarios of tidal evolution of the system. We show new scenarios of evolution of the Enceladus–Dione system through resonance not shown in previous approaches of the problem.  相似文献   

Refinement of the Micro‐Distillation Technique for Isotopic Analysis of Geological Samples with pg‐Level Osmium Contents     

Nao Nakanishi  Tetsuya Yokoyama  Akira Ishikawa 《Geostandards and Geoanalytical Research》2019,43(2):231-243

In recent years, the ¹⁸⁷Re–¹⁸⁷Os isotope system has been increasingly used to study samples containing very small quantities of Os. For such samples, optimisation of measurement procedures is essential to minimise the loss of Os before mass spectrometric measurements. Micro‐distillation is a necessary purification step that is applied after the main Os chemical separation procedure, prior to Os isotope ratio measurements by negative‐thermal ionisation mass spectrometry (N‐TIMS). However, unlike the other separation steps, this procedure has not yet been optimised for small samples. In this study, we present a refined micro‐distillation method that achieved higher yields and allowed high‐precision R(¹⁸⁷Os/¹⁸⁸Os) expressed as ¹⁸⁷Os/¹⁸⁸Os measurements for small‐sized geological samples that contain only a few pg Os. The Os recovery in the micro‐distillation step was tested by changing the operating conditions including heating time and temperature, and amounts of oxidant and reductant. Recoveries were measured by the isotope dilution ICP‐MS method after the addition of ¹⁹⁰Os‐enriched spike solution. We found that the most critical factor controlling the chemical yield of Os during micro‐distillation is the extent of dilution of the reductant (HBr) by H₂O evaporated from the oxidant. A refined micro‐distillation method, in which the amount of oxidant solution is reduced from the conventional method, achieved an improved chemical yield of Os (~ 90%). This refined method was applied to the measurement of ¹⁸⁷Os/¹⁸⁸Os by N‐TIMS of varying test portions of the geological reference material BIR‐1a. The resulting ¹⁸⁷Os/¹⁸⁸Os ratios of BIR‐1a matched the literature data, with propagated uncertainties of 0.2, 1.1 and 11% digested sample quantities containing 150, 10 and 1 pg of Os, respectively.  相似文献   

Geomagnetic studies on Volcano Mihara     

T. Rikitake  I. Yokoyama  S. Uyeda  T. Yukutake 《Bulletin of Volcanology》1963,26(1):49-55

  相似文献   

Structure of caldera and gravity anomaly     

Izumi Yokoyama 《Bulletin of Volcanology》1963,26(1):67-72

  相似文献   

A Study on the Formation of Smectite in Silica Scales Precipitated from Geothermal Water: The Effect of Magnesium     

Yoshinobu Aramaki    Takushi Yokoyama  Yoshihiro Okaue  Akira Imai  Koichiro Watanabe 《Resource Geology》2005,55(3):281-284

Abstract. Silica scales containing large amounts of smectite were recently found in the pipelines for geothermal water at a geothermal power plant. To elucidate the mechanism of smectite formation, seven silica scale samples were characterized by powder X-ray diffraction, chemical analysis and ²⁷A1 MAS NMR. Smectite was present in samples with MgO levels above 10 wt% and Al₂O₃ levels below 10 wt%. In ²⁷A1 MAS NMR spectra, peaks assigned to both tetrahedrally and octahedrally coordinated aluminum (Al(4) and Al(6)) were observed for Mg-rich samples, whereas a peak due to Al(4) alone appeared in Mg-poor samples. From these observation and comparison between ²⁷A1 MAS NMR spectra for synthesized precipitates of Al₂O₃-SiO₂ containing MgO and not containing MgO, it is concluded that magnesium plays an important role in the stabilization of Al(6), and results in the formation of smectite  相似文献   

Introduction     

S.A. Fedotov  I. Yokoyama 《Journal of Geodynamics》1985,3(3-4)

  相似文献   

Geochronology and Tectonic Evolution of Karimnagar and Bhopalpatnam Granulite Belts, Central India   总被引：1，自引：0，他引：1  

M. Santosh  K. Yokoyama  S.K. Acharyya 《Gondwana Research》2004,7(2):501-518

The Karimnagar Granulite Belt (KGB) and the Bhopalpatnam Granulite Belt (BGB) occur along both flanks of the Pranhita-Godavari (PG) rift basin. We present a state-of-the-art overview on the geochronological and tectonic aspects of these belts and surrounding geologic domains, and report new age data on zircon, monazite and uraninite recovered from granulite facies assemblages from KGB and BGB based on electron microprobe analyses (EPMA). Zircons from KGB charnockites show core ages of up to 3.1 Ga mantled by rims of 2.6 Ga. Zircons from BGB have 1.9 Ga cores mantled by 1.7 Ga rims. Zircons with core ages of 1.6 to 1.7 Ga in BGB rocks suggest new growth at this time. Monazites and uranitite from KGB show clear peaks with well-defined ages in the narrow range between 2.42±0.08 Ga and 2.47°0.03 Ga. Rims of monazite show mean age of 2.21±0.08 Ga. Monazites from BGB define sharp linear trend in PbO vs. ThO₂* diagram delineating a clear isochron with age of 1.59±0.03 Ga. Age data from KGB and BGB presented in this report negate current models linking these terrains to "Godavari Granulite Belt" and considering them as single and contemporaneous entity. The mid-Archaean to early Palaeoproterozoic signature recognized from KGB is totally missing in BGB. On the other hand, KGB rocks do not record any evidence for major Mesoproterozoic thermal regime. The two granulite belts shouldering the PG rift basin have therefore evolved in different times under distinct P-T conditions and thermal regimes. Our results have important implications in evaluating models of supercontinent assemblies, particularly the older assemblies of Ur, Columbia and Rodinia. While tectonothermal events in KGB broadly match with those of East Dharwar, we propose that BGB represents a 1.6 Ga collisional mobile belt between the Bastar and the Dharwar cratons. The 1.6 Ga collisional mobile belt at the southern margin of the Bastar craton was superposed by rift activity along the PG basin at 1.5 Ga. This sequence of events goes against the existence of a 3.0 Ga old contiguous assembly of Ur but closely matches with the history of accretion and break-up of the Columbia. Further, parts of the PG basin located away from the influence of the Eastern Ghats Mobile Belt, neither recorded any Grenville ages (1.0 Ga) corresponding to the Rodinia accretion nor late Pan-African ages (ca. 550 Ma) relating to the Gondwana amalgamation, indicating that the region did not witness any of these younger tectonic events.  相似文献   

Zonation and species diversity of smaller macrobenthos in the westernmost part of Wakasa Bay (the Sea of Tango)     

Hisashi Yokoyama  Isao Hayashi 《Journal of Oceanography》1980,36(1):46-58

Grab samples of the smaller macrobenthos (>1 mm, <1g wet weight) were obtained seasonally at fourteen stations along two transects in the shallow coastal waters of the westernmost part of Wakasa Bay. According to Morisita's similarity index (C _i , two faunal groups were recognized to be present throughout the year. The boundary between them was found to lie between depths of 10 and 20 m where the silt-clay fraction increased abruptly in the sediment, although the boundary was less obvious in summer. Statistics on community structure (species diversity, species richness, and evenness) also showed marked differences between the two assemblages. The change in faunal features was found to be roughly parallel to changes in sediment characteristics. On the nearshore sandy bottom, the influence of wave action is considered to be the major factor affecting the fauna as it results in a decrease in evenness and species richness. On the other hand, on the offshore muddy bottom, stagnant conditions cause the benthic fauna to decrease in density and to bear some resemblance to those of enclosed bays. The highest species diversity was found on the silty sand bottom (20 m deep). This can be understood as an edge effect of an ecotone.  相似文献   

河口地层独居石Th(U)-Pb年龄对长江贯通时限的约束   总被引：6，自引：0，他引：6  

范代读  李从先  Yokoyama Kazumi 《海洋地质前沿》2006,22(7):11-15

新生代长江水系调整、东西贯通时限是国内外学者共同关注的问题。长江发展演化的复杂性在近一个世纪的河流沉积地貌学研究中得到充分的认识,但在贯通时限问题上难以形成共识。河口地层中碎屑独居石的电子探针Th(U)-Pb年龄较好地限定长江东西贯通的时间在2.58MaBP前后。随着碎屑矿物微区分析技术的发展,锆石、独居石年代学和微区特征将成为研究流域演化、构造运动的主要手段。  相似文献